The wines and liqueurs and champagnes of New Orleans were new and exhilarating to her, acquainted with only homemade blackberry and scuppernong vintages and Aunt Pitty’s "swoon" brandy; but oh, the food Rhett ordered!
There are no more uses of "acquaint" in the book.
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You should acquaint yourself with the new computer program.
One of the objectives in my literature class is to acquaint my students with different cultures.